PREPARATION OF ORANGE PEELS BY INSTANT CONTROLLED PRESSURE DROP AND CHEMICAL MODIFICATION FOR ITS USE AS BIOSORBENT OF ORGANIC POLLUTANTS

  • L.A. Romero-Cano. Centro de Investigación y Desarrollo Tecnológico en Electroquímica (CIDETEQ) SC
  • L.V. Gonzalez-Gutierrez. Centro de Investigación y Desarrollo Tecnológico en Electroquímica (CIDETEQ) SC
  • L.A. Baldenegro-Perez. Centro de Ingeniería y Desarrollo Industrial (CIDESI)
  • M.I. Medina-Montes. Centro de Investigación y Estudios Avanzados del IPN (CINVESTAV)
Keywords: agroindustrial wastes, orange peels, biosorption, instant controlled pressure drop (DIC), wastewater treatment

Abstract

Some types of inactive biomass have been studied in terms of their adsorption properties as alternatives to the commonly used Activated Carbon (AC) such as orange peel. The present study evaluates a physical-chemical treatment for enhancing the adsorption capacity of raw orange peel for two model organic pollutants (azo dye and phenol). Instant Controlled Pressure Drop (“DIC” by its abbreviations in french), a vacuum drying technology, was applied as a first treatment, prior to chemical surface modification - either basic, using NaOH or acid, using Citric acid-. The use of DIC modifies and improves the structural properties of the material. Consequently, the combination of this technique followed by a chemical treatment shows an enhancement in the adsorption capacity of orange peels. The results showed that R-OH, R-COOH and R-COOCH3 groups were present on the orange peel surface according to the treatment used. DIC treatment increases the adsorption capacity of raw orange peels 285% for the azo dye and 632% for phenol; DIC treatment plus adding the chemical surface modification, increase the adsorption 640% and 1812% for azo dye and phenol, accordingly. The present research work shows a novel technique for orange peels preparation as an adsorbent material.

References

Ahmaruzzaman, M. (2008). Adsorption of phenolic compounds on low-cost adsorbents: a review. Advances in Colloid and Interface Science 143(1), 48-67.

Ahmaruzzaman, M., & Sharma, D. K. (2005). Adsorption of phenols from wastewater. Journal of Colloid and Interface Science 287, 14-24.

Alkaram, U. F., Mukhlis, A. A., & Al-Dujaili, A. H. (2009). The removal of phenol from aqueous solutions by adsorption using surfactant-modified bentonite and kaolinite. Journal of Hazardous Materials 169, 324-332.

Annadurai, G., Juang, R. S., & Lee, D. J. (2002). Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. Journal of Hazardous Materials 92, 263-274.

Arellano-Cardenas, S., Gallardo-Velázquez, T., Osorio-Revilla, G., López-Cortéz, M., & Gómez-Perea, B. (2005). Adsorption of phenol and dichlorophenols from aqueous solutions by porous clay heterostructure (PCH). Journal of the Mexican Chemical Society 49, 287-291.

Besombes, C., Berka-Zougali, B., & Allaf, K. (2010). Instant controlled pressure drop extraction of lavandin essential oils: Fundamentals and experimental studies. Journal of Chromatography A 1217, 6807-6815.

Boehm, H.P. (1994). Some aspects of the surface chemistry of carbon blacks and other. carbons. Carbon 32, 759-769.

Chatterjee, G., De Neve, J., Dutta, A., Das, S., (2015). Formulation and statistical evaluation of ready-to-drink whey based orange beverage and its storage stability. Revista Mexicana de Ingeniería Química 14, 253-264.

Crini, G. (2006). Non-conventional low-cost adsorbents for dye removal: a review. Bioresource Technology 97, 1061-1085.

Djebbar, M., Djafri, F., Bouchekara, M., & Djafri, A.(2012). Adsorption of phenol on natural clay. Applied Water Science 2, 77-86.

Faria, P. C. C., Orfao, J. J. M., & Pereira, M. F. R. (2004). Adsorption of anionic and cationic dyes on activated carbons with different surface chemistries. Water Research 38, 2043-2052.

Feng, N., Guo, X., & Liang, S. (2009). Adsorption study of copper (II) by chemically modified orange peel. Journal of Hazardous Materials 164, 1286-1292.

Feng, N. C., Guo, X. Y., & Liang, S. (2010). Enhanced Cu (II) adsorption by orange peel modified with sodium hydroxide. Transactions of Nonferrous Metals Society of China 20, s146- s152.

Gusev, S. S., & Ermolenko, I. N. (1965). Absorption spectra in the 1500-1800 and 3000-6000 cm−1 ranges for cellulose containing acetyl and carboxyl groups. Journal of Applied Spectroscopy 2, 276-278.

Jung, M. W., Ahn, K. H., Lee, Y., Kim, K. P., Rhee, J. S., Tae Park, J., & Paeng, K. J. (2001). Adsorption characteristics of phenol and chlorophenols on granular activated carbons (GAC). Microchemical Journal 70, 123-131.

Kaleta, J. (2006). Removal of phenol from aqueous solution by adsorption. Canadian Journal of Civil Engineering 33, 546-551.

Kamal, I. M., Sobolik, V., Kristiawan, M., Mounir, S. M., & Allaf, K. (2008). Structure expansion of green coffee beans using instantaneous controlled pressure drop process. Innovative Food Science & Emerging Technologies 9, 534- 541. Kamal, I., Gelicus, A., & Allaf, K. (2012). Impact of instant controlled pressure drop (DIC) treatment on drying kinetics and caffeine extraction from green coffee beans. Journal of Food Research 1, 24-27.

Karapinar, E., Phillips, D. A. S., & Taylor, J. A. (2007). Reactivity, chemical selectivity and exhaust dyeing properties of dyes possessing a 2-chloro-4-methylthio-s-triazinyl reactive group. Dyes and Pigments 75, 491-497.

Kumar, N.S., Min, K., (2011). Removal of phenolic compounds from aqueous solutions by biosorption onto acacia leucocephala bark powder: Equilibrium and kinetic studies. Journal of the Chilean Chemical Society 56, 539-545.

Li, X., Tang, Y., Xuan, Z., Liu, Y., & Luo, F. (2007). Study on the preparation of orange peel cellulose adsorbents and biosorption of Cd2+ from aqueous solution. Separation and Purification Technology 55, 69-75.

Louka, N., & Allaf, K. (2004). Expansion ratio and color improvement of dried vegetables texturized by a new process controlled sudden decompression to the vacuum: application to potatoes, carrots and onions. Journal of Food Engineering 65, 233-243.

Lu, D., Cao, Q., Li, X., Cao, X., Luo, F., & Shao, W. (2009). Kinetics and equilibrium of Cu (II) adsorption onto chemically modified orange peel cellulose biosorbents. Hydrometallurgy 95, 145-152.

Maradiya, H. R. (2010). Synthesis and dyeing performance of some novel thiazole azo disperse dyes. Journal of Saudi Chemical Society 14, 77-81.

Namasivayam, C., & Kavitha, D. (2006). IR, XRD and SEM studies on the mechanism of adsorption of dyes and phenols by coir pith carbon from aqueous phase. Microchemical Journal 82, 43-48.

Romero-Cano, L.A., Gonzalez-Gutierrez, L. V., Baldenegro-Pérez, L.A., (2016). Biosorbents prepared from orange peels using Instant Controlled Pressure Drop for Cu(II) and phenol removal. Industrial Crops and Products 84, 344-349.

Polat, H., Molva, M., & Polat, M. (2006). Capacity and mechanism of phenol adsorption on lignite. International Journal of Mineral Processing 79, 264-273.

Setyopratomo, P., Fatmawati, A., & Allaf, K. (2009). Texturing by instant controlled pressure drop DIC in the production of cassava flour: impact on dehydration kinetics, product physical properties and microbial decontamination. In Proceedings of the World Congress on Engineering and Computer Science. San Francisco, USA.

Sha, L., Xueyi, G., Ningchuan, F., & Qinghua, T. (2009). Adsorption of Cu2+ and Cd2+ from aqueous solution by mercapto-acetic acid modified orange peel. Colloids and Surfaces B: Biointerfaces 73, 10-14.

Wang, J., Huang, C., Allen, H., Cha, D., Kim, D., (1998). Adsorption Characteristics of Dye onto Sludge Particulates. Journal of Colloid Interface Science 208, 518-528.

Yousef, R. I., El-Eswed, B., & Al-Muhtaseb, A. A. H. (2011). Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions: kinetics, mechanism, and thermodynamics studies. Chemical Engineering Journal 171, 1143-1149.
Published
2020-01-08
How to Cite
Romero-Cano., L., Gonzalez-Gutierrez., L., Baldenegro-Perez., L., & Medina-Montes., M. (2020). PREPARATION OF ORANGE PEELS BY INSTANT CONTROLLED PRESSURE DROP AND CHEMICAL MODIFICATION FOR ITS USE AS BIOSORBENT OF ORGANIC POLLUTANTS. Revista Mexicana De Ingeniería Química, 15(2), 481-491. Retrieved from http://www.rmiq.org/ojs311/index.php/rmiq/article/view/1146
Section
Food Engineering