• A. Topete -Betancourt
  • J. D. Figueroa
  • E. Morales Sanchez
  • G. Arámbula-Villa
  • J. F. Pérez-Robles
Keywords: Fickian mechanism, Diffusion coefficient, Water release, Oil absorption, Tortilla chips


Simple equation Mt/M= Ktn is evaluated to describe the Fickian mechanism of oil absorption and water release during the frying of tortilla chips in nixtamalized samples with lime and without lime where Mt/M is the fractional solute absorption or release, and n is the diffusional exponent characteristic of the Fickian mechanism that changes with food physical and chemical properties. For the Fickian mechanism, the exponent (n) is ≤0.50, and non-Fickian is 0.5<n<1 for slabs. Moisture releases showed a Fickian mechanism form tortilla chips with lime (n = 0.5) due to water interaction with matrix components and non-Fickian for tortilla chips without lime (n = 0.6). Oil absorption showed a Fickian mechanism for nixtamalization with lime n = 0.4 and for nixtamalization without lime, one of n = 0.3. The larger water diffusion coefficient in the tortilla chip compared to that of oil diffusion indicates that water release and oil absorption during frying is not a simultaneous event. The behavior of the water and oil diffusion is an interesting topic that, in this study, was investigated using a practical equation with potential application in food processing.


AACC International. 2010. Approved Methods of Analysis, 11th Ed. Methods 44-19.01, 30-10.01. Available online only. AACC Int: St. Paul, MN, USA.

Arámbula, V. G., Mauricio, S. R. A., Figueroa, J. D. C., González-Hernández, J., and Ordorica, F.C.A. (1999). Corn masa and tortilla from extruded instant corn flour containing hydrocolloids and lime. Journal of Food Science 64, 120-124.

Arámbula, V. G., Yáñez-Limón, J. M., Vorobiev-Vasilievich, Y., and González-Hernández, J. (2000). Effective moisture diffusion coefficient of nixtamalized corn masa by extrusion. Agrociencia 34, 717-727.

Aslani, P. and Kennedy, R. A. (1996). Studies on diffusion in alginate gels. I. Effect of cross-linking with calcium or zinc ions on diffusion of acetaminophen. Journal of Controlled Release 42, 75-82.

Blumenthal, M. M. and Stier, R. F. (1991). Optimization of deep-fat frying operations. Trends in Food Science and Technology 2, 144-148.

Bouchon, P., Aguilera, J. M. and Pyle, D. L. (2003). Structure oil absorption relationships during deep-fat frying. Journal of Food Science 68, 2711-2716.

Bouchon, P. and Pyle, D. L. (2004). Studying oil absorption in restructured potato chips. Journal of Food Science 69, 115-122.

Bryant, C. M. and Hamakar, B. R. (1997). Effect of lime on gelatinization of corn flour and starch. Cereal Chemistry 74, 171-175.

Chen, Y. and Moreira, R. G. (1997). Modelling of a batch deep-fat frying process for tortilla chips. Food and Bioproducts Processing 75, 181-190.

Chen, G., Maier, D. E., Campanella, O. H. and Takhar, P. S. (2009). Modeling of moisture diffusivities for components of yellow-dent corn kernels. Journal of Cereal Science 50, 82–90.

Chou, D. H. and Morr, C. V. (1976). Protein-Water Interactions and Functional Properties. Journal of the American Oil Chemists' Society 56, 53-62.

Contreras-Jiménez, B., Gaytán-Martínez, M., Figueroa-Cárdenas, J. D., Avalos-Zúñiga, R. A. and Morales-Sánchez, M. (2014). Effect of steeping time and calcium hydroxide concentration on the water absorption and pasting profile of corn grits. Journal of Food Engineering 122, 72-77.

Cornejo-Villegas, M. A., Rincon-Londoño, N. R., Real-Lopez, A. and Rodríguez-Garcia, M. E. (2018). The effect of Ca2++ ions on the pasting, morphological, structural, vibrational, and mechanical properties of corn starchewater system. Journal of Cereal Science 79, 174-182.

Crank, J. (1975). ¨The Mathematics of Diffusion¨. 2nd Ed., Clarendon Press.

Ding-Bing, H., Fei, X., Tse-Chao, H. and Xiao-Yan, S. (2013). Oil absorption mechanism of fried food during cooling process. Journal of Food Process Engineering 36, 412-417.

Enscore, D. J., Hopfenberg, H. B. and Stannett, V. T. (1977). Effect of particle size on the mechanism, controlling n-hexane sorption in glassy polystyrene microspheres. Polymer 18, 793-800.

Fan, L. P., Zhang, M., Xiao, G. N., Sun, J. C. and Tao, Q. (2005). The optimization of vacuum frying to dehydrated carrot chips. International Journal of Food Science and Technology 40, 911–919.

Flores-Martinez, N. L., Perez-Perez, M. C. I., Oliveros-Muñoz, J. M., Lopez-Gonzalez, M. L. and Jimenez-Islas, H. (2018). Estimation of diffusion coefficients of essential oil of Pimenta dioica in edible films formulated with Aloe vera and gelatin, using levenberg-marquardt method. Revista Mexicana de Ingenieria Quimica 17, 485-506.

Gallegos-Marin, I., Mendez-Lagunas, L. L., Rodriguez-Ramirez, J. and Martinez-Sanchez, C. E. (2016). Structural properties changes during osmotic drying of plantain (Musa paradisiaca AAB) and its role on mass transfer. Revista Mexicana de Ingenieria Quimica 15, 441-456.

Goyary, J., Kumar, A. and Nayak, P. K. (2015). Changes of quality parameters of soybean oil in deep fat frying: A review. Journal of Basic and Applied Engineering Research 2, 951-954.

Grabowska, B., Sitarz, M., Olejnik, E. and Kaczmarska, K. (2015). FT-IR and FT-Raman studies of cross-linking processes with Ca2+ ions, glutaraldehyde and microwave radiation for polymer composition of poly(acrylic acid)/sodium salt of carboxymethyl starch – Part I. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 135, 529–535.

Halder, A., Dhall, A. and Datta, A. K. (2007). An improved, easily implementable, porous media based model for deep-fat frying. Part I: Model development and input parameters. Food and Bioproducts Processing 85, 2009-219.

Higuchi, T. (1961). Rate of release of medicaments from ointment bases containing drugs in suspension. Journal of Pharmaceutical Sciences 50, 874-875.

Higuchi, T. (1963). Theoretical analysis of rate of release of solid drugs dispersed in solid matrices. Journal of Pharmaceutical Sciences 52, 1145-1149.

Kochhar, P. and Gertz, C. (2004). New theoretical and practical aspects of the frying process. European Journal of Lipid Science and Technology 106, 722–727.

Korsmeyer, R. W. and Peppas, N. A. (1981). Effect of the morphology of hydrophilic polymeric matrices on the diffusion and release of water soluble drugs. Journal of Membrane Science 9, 211-227.

Krokida, M. K., Oreopoulou, V. and Maroulis, Z. B. (2000). Water loss and oil uptake as a function of frying time. Journal of Food Engineering 44, 39-46.

Maitra, J. and Shukla, V. K. (2014). Cross-linking in Hydrogels - A Review. American Journal of Polymer Science 4, 25-31.

Mandema, W. and Zeldenrust, H. (1977). Diffusion of polystyrene in tetrahidrofuran. Polymer 18, 835-839.

Mohan, R. V. N., Delaney, R. A. and Mermelstein, N. (1995). An engineering perspective on deep-fat frying of breaded chicken pieces: Engineering aspects of deep-fat frying of foods. Food Technology 49, 138-141.

Moreira, G. R. and Barrufet, M. A. (1996). Spatial distribution of oil after deep-fat frying of tortilla chips from a stochastic model. Journal of Food Engineering 27, 279-290.

Moreira, R. G., Palau. J. and Sun, X. (1995). Simultaneous heat and mass transfer during the deep fat frying of tortilla chips. Journal of Food Process Engineering 18, 307-320.

Moreira, R. G., Sun, X. and Chen, Y. (1997). Factors affecting oil uptake in tortilla chips in deep-fat frying. Journal of Food Engineering 31, 485-498.

Moreno-Castro, L. E., Quintero-Ramos, A., Ruiz-Gutierrez, M. C., Sanchez-Madrigal, M. A., Melendez-Pizarro, C. O., Perez-Reyes, I. and Lardizabal-Gutierrez, D. (2015). Nixtamalization assisted with ultrasound: Effect on mass transfer and physicochemical properties of nixtamal, masa and tortilla. Revista Mexicana de Ingenieria Quimica 14, 265-279.

Moussa, I. S. and Cartilier, L. H. (1996). Characterization of moving fronts in cross-linked amylose matrices by image analysis. Journal of Controlled Release 42, 47-55.

Ni, H. and Datta, A. K. (1999). Moisture oil and energy transport during deep-fat frying of food materials. Food and Bioproducts Processing 77, 194-204.

Olguin-Rojas, J. A., Vazquez-Leon, L. A., Salgado-Cervantes, M. A., Fernandez Barbero, G., Garcia-Alvarada, M. A. and Rodriguez-Jimenes, G. C. (2019). Water and phytochemicals dynamic during drying of red habanero chili pepper (Capsicum chinese) slices. Revista Mexicana de Ingenieria Quimica 18, 851-864.

Peppas, N. A. (1985). Analysis of Fickian and no-Fickian drug release from polymers. Journal of Pharmaceutical Sciences 60, 110-111.

Ritger, P. L. and Peppas, N. A. (1987a). A simple equation for description of solute release I. Fickian and non-Fickian release from non-swellable devices in the form slabs, spheres, cylinders or discs. Journal of Controlled Release 5, 23-36.

Ritger, P. L. and Peppas, N. A. (1987b). A simple equation for description of solution release II. Fickian and anomalous release from swellable devices. Journal of Controlled Release 5, 37-42.

Rubnov, M. and Saguy, I. S. (1997). Fractal analysis and crust water diffusivity of a restructured potato product during deep-fat frying. Journal of Food Science 62, 135-154.

Santiago-Ramos, D., Figueroa-Cárdenas, J. F. C., Mariscal-Moreno, R. M., Escalante-Aburto, A., Ponce-García, N. and Véles-Medina J. J. (2018). Physical and chemical changes undergone by pericarp and endosperm during corn nixtamalization-A review. Journal of Cereal Science 81, 108-117.

Siepmann, J. and Peppas, N. A. (2011). Higuchi equation: derivation, applications, use and misuse. International Journal of Pharmaceutics 418, 6-12.

Soppirnath, K. S., and Aminabhavi, T. M. (2002). Water transport and drug release study from cross-linked polyacrylamide grafted guar gum hydrogel microspheres for the controlled release application. European Journal of Pharmaceutics and Biopharmaceutics. 53, 87-98.

Stier, R. F. (2004). Frying as a science - an introduction. European Journal of Lipid Science and Technology 106, 715–721.

Tomasula, P. M. and Craig, J. C. (1991). Correlation of moisture and oil concentration in French fries. Lebensmittel-Wissenschaft + Technology 24, 445-448.

Tong, C. H. and Lund, D. B. (1990). Effective moisture diffusivity in porous materials as a function of temperature and moisture content. Biotechnology Progress 6, 67-75.

How to Cite
Topete -Betancourt, A., Figueroa, J., Morales Sanchez, E., Arámbula-Villa, G., & Pérez-Robles, J. (2019). EVALUATION OF THE MECHANISM OF OIL UPTAKE AND WATER LOSS DURING DEEP-FAT FRYING OF TORTILLA CHIPS. Revista Mexicana De Ingeniería Química, 19(1), 409-422. https://doi.org/10.24275/rmiq/Alim605
Food Engineering

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